![Dimethylammonium dichlorotri(mu-chloro)bis{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}diruthenate(II) [NH2Me2][{RuCl((R)-dm-segphos?)}2(mu-Cl)3],二甲基铵二氯三（μ-氯）双{（R） - （+）-5,5' - 双[二（3,5 - 二甲苯基）膦基] -4,4' - 双-1,3 - 苯并间二氧杂环戊烯}二钌（II）](https://static.jkchemical.com/Structure/109/1094058.png)
二甲基铵二氯三（μ-氯）双{（R） - （+）-5,5' - 双[二（3,5 - 二甲苯基）膦基] -4,4' - 双-1,3 - 苯并间二氧杂环戊烯}二钌（II）
Dimethylammonium dichlorotri(mu-chloro)bis{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}diruthenate(II) [NH2Me2][{RuCl((R)-dm-segphos?)}2(mu-Cl)3]
分子式: (CH3)2NH2+[C92H88Cl5O8P4Ru2]ae
分子量: 1870.06
纯度: null
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Technical Notes:
1. Biaryl bisphosphine ligand with narrow dihedral angle. The DM-S EGPHOS® ligand, as the ruthenium complex, gives superior
enantioselectivity and diastereoselectivity in the asymmetric hydrogenation of a-substituted-ß-ketoesters. See 15-0066.
2.Ruthenium catalyzed enantioselective synthesis of ß amino acids by hydrogenation
3.Ruthenium catalyzed asymmetric hydrogenation of 3-quinuclidinone. See 44-0098 for Ru catalyst.
References:
1. U.S. Pat. 7626034.
2. U.S. Pat 7462722.
