Technical Note:

1. Ligand for the palladium-catalyzed asymmetric coupling of potassium crotyltrifluoroborate with

methyl 4-bromobenzoate

2.Ligand for the nickel-catalyzed , enantioselective, C-acylation of a-substituted lactams.

3.Ligand for Pd-catalyzed Enantioselective Conjunctive Cross-Coupling between Grignard-Derived Boron "Ate" Complexes and C(sp2) Halides or Triflates.

4.Ligand for Pd-catalyzed Asymmetric Conjunctive Cross-Coupling of Bis(alkenyl)borate Complexes.

References:

1.Organometallics, 2009, 28, 152.

2.J. Am. Chem. Soc., 2016, 138, 8997.

3.J. Am. Chem. Soc. 2017, 139, 3153-3160.

4.J. Am. Chem. Soc. 2017, 139, 5027-5030.