Technical Notes:

1. Ligand used in the enantioselective, rhodium-catalyzed hydrogenation of substituted olefins, such as N-acetyldihydroamino acids, enamides, and unsaturated acids.

2. Ligand used in the enantioselective, iridium- catalyzed allylic substitution of allyl acetates containing only a single substituent

3.Ligan use in the rhodium-catalvzed. amide

4 Ligand usedithaesrhodericataluaate additiodrecaed' boronieatciastdaingatinitronathtalenes

5: Ligand used in the rhoaium-cataiyaea asymmetricaintramoieculari, aditionitronaphtn

References:

1.J. Am. Chem. Soc., 2000, 122, 11 539.

2.Adv. Synth. ( atal., 2003, 345, 308.

3.Adv. Synth. Catal., 2002, 344, 1003.

4.Chem. Comm, 1999, 741.

5.Eur. J. Inorg. Chem., 2002, 2569.

6.J. Am. Chem. Soc., 2008, 1 3o, 3734.

7.Ad. Synth. Catal, 2012, 354, 2433.

8.J. Org. Chem., 2013, 78, 2736.