(S)-(+)-(3,5-二氧-4-磷环己基[2,1-a;3,4-a']4-二萘基)哌啶 , min. 97%
(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a;3,4-a']dinaphthalen-4-yl)piperidine, min. 97% (S)-PipPhos
分子式: C25H22NO2P
分子量: 399.42
纯度: min. 97%
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Technical Notes:
1.See 15-1232
2. L igand used in the enantioselective rhodium catalyzed low pressure high activity hydrogenation of a dehydroaminoesters, enamides, and dimethylitaconate.
3. Ligand used in asymmetric hydrogenation of 2-substituted N-protected indoles using Rhodium-based catalysts.
References:
1.J. Org. Chem.. 2005, 70, 943. 2.Tetrahedron, 2010, 21,7
3.Organometallics, 2011. 30. 1942 4. 4.Adv. Synth. Catal., 2011, 353.