![Dichloro[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]palladium(II), min. 98%,[(R)-(+)-2,2'-双(二苯基膦)-1,1'-联萘]二氯化钯 , min. 98%](https://static.jkchemical.com/Structure/128/128631.png)
[(R)-(+)-2,2'-双(二苯基膦)-1,1'-联萘]二氯化钯 , min. 98%
Dichloro[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]palladium(II), min. 98%
分子式: PdCl2(C44H32P2)
分子量: 800.00
纯度: min. 98%
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Technical Notes:
1. Catalyst precursor, with AgBF4. for the enantioselective addition of silyl ethers, to imines to produce ß- amino ketones, and t aldehydes to produce 3-hydroxy-1-propanone aldol addition products
2. Catalyst precursor, with AgSbFe, for the asymmetric carbonylene reaction,
3.Catalyst precursor for hetero Diels-Alder reaction of simple dienes with aldehydes and aryl glyoxals .
References:
1. J. Am. Chem. Soc.. 1999, 12, 15450.
2.Tetrahedron L ett. 2006, 47. 3956.
3.Organometallics, 2007. 26, 5961.
4.Tetrahedron, Asymm., 2004.15, 3885.
5.Tetrahedron Lett. 1998, 39, 6253.
6. J. Org. Chem., 1999 648660.
