三(丙腈基)伍甲基环戊二烯基钌 (II) 六氟磷酸 , min. 98%
Tris(acetonitrile)pentamethylcyclopentadienylruthenium(II) hexafluorophosphate, min. 98%
分子式: [Ru(C10H15)(CH3CN)3]+PF6ae
分子量: 504.42
纯度: min. 98%
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Technical Notes:
1.Useful catalyst for the hydrosilylation of internal and terminal alkynes. The reaction has also been extended to intramolecular hydros ilylation.
2Catalyst for the cyclois omerization of diynes .
3.Catalyst for synthesis of furans from bis(alkynes) and DMSO.
R eferences:
1.J. Am. Chem. Soc., 2001, 123, 12726.
2.J. Am. Chem. Soc, 2003, 125, 30.
3.J. Am. Chem. Soc., 2005, 127, 4763 .
4.J. Am. Chem. Soc., 2012, 134, 7660.