ruthenium(II) chloride [RuCl(p-cymene)((R)-H8-binap)]Cl,氯[(R)-(+)-2,2′-双(二苯基膦)-5,5′,6,6′,7,7′,8,8′-八氢-1,1′-联萘](p-伞花素)氯化钌(II)](https://static.jkchemical.com/Structure/807/807509.png)
氯[(R)-(+)-2,2′-双(二苯基膦)-5,5′,6,6′,7,7′,8,8′-八氢-1,1′-联萘](p-伞花素)氯化钌(II)
Chloro[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl](p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((R)-H8-binap)]Cl
分子式: [C54H54ClP2Ru]+Clae
分子量: 936.93
纯度: null
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基本信息
安全信息
化学和物理性质
产品描述
Technical Notes:
1.. Biary bisphosphine ligand. The Hg-BINAP ligand, as the ruthenium complex, catalyzes hydrogenation of unsaturated carboxylic acids to a higher ee than does BINAP. (Ref. 1,2)
2. The ruthenium catalyzed hydrogenation of aryl propenoic acid to produce the drug lbuprofen.
References: 1. J. Org. Chem., 1996, 61, 5510. 2.Topics Organometal. Chem. 2004, 6, 63 (review).
