![(R)-4-(Anthracen-9-yl)-3-(t-butyl-2,3-dihydrobenzo[d][1,3]oxaphosphole, 97% (>99% ee) [(R)-AntPhos],R)-4-(蒽-9-基)-3-(叔丁基-2,3-二氢苯并[d] [1,3]氧杂磷杂环孔,98 +%(> 99%ee)[(R)-AntPhos] , 97% (>99% ee)](https://static.jkchemical.com/Structure/244/2446371.png)
R)-4-(蒽-9-基)-3-(叔丁基-2,3-二氢苯并[d] [1,3]氧杂磷杂环孔,98 +%(> 99%ee)[(R)-AntPhos] , 97% (>99% ee)
(R)-4-(Anthracen-9-yl)-3-(t-butyl-2,3-dihydrobenzo[d][1,3]oxaphosphole, 97% (>99% ee) [(R)-AntPhos]
分子式: C25H23OP
分子量: 370.42
纯度: 97% (>99% ee)
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Technical Notes:
1. Ligand/palladium catalyst for general Miyaura borylation reactions .
2. Ligand/palladium catalyst for general and sterically demanding Suzuki-Miyaura cross-couplingreactions.
3. L igand/palladium catalyst for aryl-alkyl Suzuki-Miyaura cross-coupling reactions.
4. Ligand/nickel catalyst for intramolecular reductive cyclization.
5. Ligand/palladium catalyst for Dearomative cyclization.
References:
1. Org. Lett., 2011, 13,1366.
2. Chem. Eur. J., 2013. 19.2261.
3. Org. Chem. Front., 2014,1, 225.
4. Angew. Chem. Int. Ed., 2015, 54.2520.
5. Angew. Chem. Int. Ed., 2015, 54, 3033.
6. Tetrahedron, 2016, 72, 1 782.