(11bR)-4-羟基-2,6-二甲基-2-萘基-4-氧化物二萘并[2,1-d:1',2'-f][1,3,2]二噁磷杂庚英 , 98%
(11bR)-4-Hydroxy-2,6-di-2-naphthalenyl-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin, 98%, (99% ee)
分子式: C40H25O4P
分子量: 600.6
纯度: 98%
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Technical Notes:
1.aza-Michael Addition: Catalyst for the enantioselective aza-Michael addition of aromatic amines to nitroolefins.
2.Cycloaddition: A chiral phos phoric acid- catalyzed intramolecular 1,3-dipolar cycloaddition of 4-(2-
formylphenoxy )butenoates with amino esters provides hexahydromeno4 , 3-bpyrrolidine derivatives in high enantioselectivity (up to 94% ee)
References:
1.Chinese J Catal, 2011, 32, 1573-1576.
2.Org. Biomol. Chem., 2010, 8, 2016-2019.