![N-[3,5-Bis(trifluoromethyl)phenyl]-N'-[(1R,2S)-2,3-dihydro-2-hydroxy-1H-inden-1-yl]thiourea, 95%, (99% ee),N-[3,5-双(三氟甲基)苯基]-N'-[(1R,2S)-2,3-二氢-2-羟基-1H-茚-1-基]硫脲 , 95%, (99% ee)](https://static.jkchemical.com/Structure/910/9108732.png)
N-[3,5-双(三氟甲基)苯基]-N'-[(1R,2S)-2,3-二氢-2-羟基-1H-茚-1-基]硫脲 , 95%, (99% ee)
N-[3,5-Bis(trifluoromethyl)phenyl]-N'-[(1R,2S)-2,3-dihydro-2-hydroxy-1H-inden-1-yl]thiourea, 95%, (99% ee)
分子式: C18H14F6N2OS
分子量: 420.40
纯度: 95%, (99% ee)
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Technical Notes:
1.Friedel-Crafts Alkylation- access to optically active 2-indolyl-1 -nitro derivatives by enantioselective Friedel- Crafts alkylation of indoles with nitroalkenes (R1= R2=- H, R3= Ph).
2.Conjugate Addition- Conjugate addition of O-protected hydroxylamines to pyrazole -derived enoates
proceeds with high efficiency and enantioselectivity.
References ：
1. Angew. Chem Int. Ed, 2005, 44, 6576-6579. J. Ãm. Chem. Soc., 2007, 129, 8064 -8065.
