[S(R)]-N-[(1S)-2-(二苯基膦基)-1- [2-(二苯基膦基苯基)乙基] -2-甲基-2-丙烷亚磺酰胺,95% , 95%
[S(R)]-N-[(1S)-2-(Diphenylphosphino)-1-[2-(diphenylphosphino)phenyl]ethyl]-2-methyl-2-propanesulfinamide, 95%
分子式: C36H37NOP2S
分子量: 593.7
纯度: 95%
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Technical Notes:
1.Chiral sulfinamide bis phosphine ca talysts for highly enantioselective intermolecular cross -Rauhut-Currierreactions.
2.Used in phosphine-catalyzed asymmetric intermolecular cross-vinylogous Rauhut-Currier Reactions of vinyl Ketones with para-quinone methides .
3.Used in the enantioselective phosphine-catalyzed allylic alkylations of mix-indene with MBH carbonates .
4.Ligand for the Pd-catalyzed fast and living polymerizations of various diazoacetate monomers under mildconditions.
5.Ligand for the direct Pd-catalyzed cross-coupling reaction of easily accessible secondary phosphine oxides and aryl bromides, which provides rapid access to P-chiral phosphine oxides.