新污染物聚焦——药物及个人护理品PPCPs
时间: 2024-06-11
作者: 百灵威
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PPCPs（Pharmaceuticals and Personal Care Products）主要源自人类使用的药物和个人护理产品，其中药物包括各种处方和非处方药物，如抗生素类、激素类、消炎止痛药、降压降血脂类、抗精神类药等；个人护理品包括含抗菌剂、消毒剂、紫外线吸收剂、防腐剂和驱虫剂等。
PPCPs通过污水处理厂、垃圾填埋场等途径进入水环境中，在水环境中可长期存在，表现出慢性毒性、伪持久性和生物累积性，可通过生物富集及食物链传递作用对生态系统与人类健康造成危害。
PPCPs作为一类新污染物，对其进行研究和监测是环境科学领域的重要课题之一。百灵威可供应近十类上百种PPCPs标准物质，同时可供应PPCPs分析常用试剂耗材。
药品类标准物质
抗生素| 品名 | CAS | 货号 |
|---|---|---|
| Azithromycin, 98%, reference material 阿奇霉素 | 83905-01-5 | 963892 |
| Chloramphenicol, 99.5%, reference material 氯霉素 | 56-75-7 | 912378 |
| Cinoxacin, 98%, reference material 西诺沙星 | 28657-80-9 | 999921 |
| Ciprofloxacin, 98%, reference material 环丙沙星 | 85721-33-1 | 986785 |
| Clindamycin, 99%, reference material 克林霉素 | 18323-44-9 | 491090 |
| Doxycycline, 98%, reference material 强力霉素 | 564-25-0 | 101324 |
| Florfenicol, 98%, reference material 氟苯尼考 | 73231-34-2 | 906582 |
| Nalidixic acid, 99.5%, reference material 萘啶酸 | 389-08-2 | 993394 |
| Norfloxacin, 98%, reference material 诺氟沙星 | 70458-96-7 | 959694 |
| Ofloxacin, 99%, reference material 氧氟沙星 | 82419-36-1 | 916029 |
| Oxolinic acid, 98%, reference material 噁喹酸 | 14698-29-4 | 949420 |
| Oxytetracycline, 97%, reference material 土霉素 | 79-57-2 | 910069 |
| Pipemidic acid, 98%, reference material 吡哌酸 | 51940-44-4 | 465587 |
| Roxithromycin, 98%, reference material 罗红霉素 | 80214-83-1 | 982370 |
| Sparfloxacin, 99%, reference material 司帕沙星 | 110871-86-8 | 500621 |
| Sulfachloropyridazine, 97%, reference material 磺胺氯哒嗪 | 80-32-0 | 367197 |
| Sulfadiazine, 99%, reference material 磺胺嘧啶 | 68-35-9 | 907349 |
| Sulfadimethoxine, 98%, reference material 磺胺地索辛 | 122-11-2 | 961285 |
| Sulfadimethoxine, 98%, reference material 磺胺地索辛 | 122-11-2 | 961285 |
| Sulfamerazine, 98%, reference material 磺胺甲基嘧啶 | 127-79-7 | 236883 |
| Sulfamethizole, 98%, reference material 磺胺甲二唑 | 144-82-1 | 315878 |
| Sulfamethoxazole, 99.5%, reference material 磺胺甲基噁唑 | 723-46-6 | 926830 |
| Sulfisoxazole, 99%, reference material 磺胺异噁唑 | 127-69-5 | 961194 |
| Thiamphenicol, 99%, reference material 甲砜霉素 | 15318-45-3 | 950887 |
降压药
| 品名 | CAS | 货号 |
|---|---|---|
| Amlodipine, 98%, reference material 氨氯地平 | 88150-42-9 | 447075 |
| Felodipine, 98%, reference material 非洛地平 | 72509-76-3 | 959553 |
| Nisoldipine, 98%, reference material 尼索地平 | 63675-72-9 | 160563 |
| Nifedipine, 98%, reference material 硝苯地平 | 21829-25-4 | 917076 |
| Nitrendipine, 98.5%, reference material 尼群地平 | 39562-70-4 | 987417 |
| Nimodipine, 99%, reference material 尼莫地平 | 66085-59-4 | 938153 |
| Reserpine, 98% 利血平 | 50-55-5 | 133388 |
| 品名 | CAS | 货号 |
|---|---|---|
| Gliclazide, 99%, reference material 格列齐特 | 21187-98-4 | 996833 |
| Glimepiride, 99%, reference material 格列美脲 | 93479-97-1 | 962565 |
| Glipizide, 98%, reference material 格列吡嗪 | 29094-61-9 | 968255 |
| Gliquidone, 98%, reference material 格列喹酮 | 33342-05-1 | 915599 |
| Glyburide, 98%, reference material 格列本脲 | 10238-21-8 | 986055 |
| Repaglinide, 98%, reference material 瑞格列奈 | 135062-02-1 | 916632 |
| Rosiglitazone, 98% 罗格列酮 | 122320-73-4 | 142624 |
| Tolbutamide, 98%, reference material 甲苯磺丁脲 | 64-77-7 | 926877 |
| Valsartan, 99%, reference material 缬沙坦 | 137862-53-4 | 974250 |
| 品名 | CAS | 货号 |
|---|---|---|
| 4-Acetamidophenol, 98.5%, a selective cyclooxygenase-2 inhibitor 4-乙酰氨基苯酚 | 103-90-2 | 508902 |
| Bezafibrate, 98%, an agonist of PPAR, with EC50s of 50 μM, 60 μM, 20 μM for human PPARα, PPARγ and PPARδ, and 90 μM, 55 μM, 110 μM for murine PPARα, PPARγ and PPARδ, respectively 苯扎贝特 | 41859-67-0 | 213579 |
| Gemfibrozil, 98% 吉非罗齐 | 25812-30-0 | 169859 |
| Ketoprofen, 98%, a COX1/2 inhibitor 酮洛芬 | 22071-15-4 | 922677 |
| Loxoprofen, 99%, a non-steroidal drug, reagent, for R&D 洛索洛芬 | 68767-14-6 | 375221 |
| Mefenamic acid, 98%, a non-steroidal anti-inflammatory agent, acting as a competitive inhibitor of hCOX-1 and hCOX-2, with IC50s of 40 nM and 3 μM for hCOX-1 and hCOX-2, respectively 甲芬那酸 | 61-68-7 | 585483 |
| Piroxicam, 98%, a non-selective COX inhibitor 吡罗昔康 | 36322-90-4 | 458307 |
| Sulindac, 99%, reference material 舒林酸 | 38194-50-2 | 995699 |
| Tenoxicam, 98% 替诺昔康 | 59804-37-4 | 181706 |
| 品名 | CAS | 货号 |
|---|---|---|
| 1-Adamantanamine hydrochloride, 99%, reference material 1-金刚烷胺盐酸盐 | 665-66-7 | 906778 |
| Imiquimod, 99.5%, reference material 咪喹莫特 | 99011-02-6 | 947936 |
| Oseltamivir, 99% 奥司他韦 | 196618-13-0 | 586004 |
| 品名 | CAS | 货号 |
|---|---|---|
| Acetylsalicylic acid, 99%, an irreversible COX1 and COX2 inhibitor 乙酰水杨酸 | 50-78-2 | 298969 |
| 4-Acetamidophenol, 98.5%, a selective cyclooxygenase-2 inhibitor 4-乙酰氨基苯酚 | 103-90-2 | 508902 |
| Diclofenac, 99.9%, reference material 双氯芬酸 | 15307-86-5 | 954863 |
| Naproxen, 99% 萘普生 | 22204-53-1 | 919368 |
| Ibuprofen, 98%, an anti-inflammatory inhibitor targeting COX-1 and COX-2 布洛芬 | 15687-27-1 | 408218 |
| Indomethacin, 98%, a nonselective COX1 and COX2 inhibitor 吲哚美辛 | 53-86-1 | 474412 |
| 品名 | CAS | 货号 |
|---|---|---|
| Carbamazepine, 97%, a sodium channel blocker 卡马西平 | 298-46-4 | 155711 |
| 品名 | CAS | 货号 |
|---|---|---|
| Estrone, 99%, reference material 雌酮 | 53-16-7 | 956191 |
| β-Estradiol, 99%, reference material β-雌二醇 | 50-28-2 | 945392 |
| Estriol, 98.5%, reference material 雌三醇 | 50-27-1 | 949275 |
个人护理品类标准物质
抗菌剂| 品名 | CAS | 货号 |
|---|---|---|
| Clotrimazole, 99% 克霉唑 | 23593-75-1 | 496300 |
| Triclocarban 3,4,4'-三氯均二苯脲（标准品） | 101-20-2 | BIOC-014N-25MG |
| Triclosan 三氯生（标准品） | 3380-34-5 | PCC-001N |
| 品名 | CAS | 货号 |
|---|---|---|
| DEET (Off) 避蚊胺（标准品） | 134-62-3 | P-255NB-250 |
PPCPs分析常用试剂
| 品名 | CAS | 货号 |
|---|---|---|
| Methanol, 99.9%, LC-MS 甲醇 | 67-56-1 | 958209 危化品 |
| Acetonitrile, 99.9%, LC-MS 乙腈 | 75-05-8 | 912457 危化品 |
| Formic acid, 98%, for LC-MS 甲酸 | 64-18-6 | 942988 危化品 |
| Ethylenediaminetetraacetic acid disodium salt dihydrate, 99%, for analysis 乙二胺四乙酸二钠盐二水合物 | 6381-92-6 | 976151 |
| Ammonium hydroxide, for analysis, 25-28% 氢氧化铵 | 1336-21-6 | 921637 危化品 |
| Citric acid, 98%, anhydrous 柠檬酸 | 77-92-9 | 947677 |
| Sodium phosphate dibasic, 99%, ACS reagent 磷酸氢二钠 | 7558-79-4 | 947717 |
| Sodium dihydrogen phosphate, 99% 磷酸二氢钠 | 7558-80-7 | 938365 |
| Sodium hydroxide, 96%, for analysis, granular 氢氧化钠 | 1310-73-2 | 970488 危化品 |
PPCPs分析常用耗材
| 品名 | CAS | 货号 |
|---|---|---|
| Delishell C18 HPLC column, 100×4.6 mm 2.6μm C18核壳液相色谱柱 | / | 9337268 |
| HLB SPE Cartridges, bed wt. 200 mg, volume 6 ml, 30 pcs/pack HLB 固相萃取小柱 | / | 948068 |
| MAX SPE Cartridges, bed wt. 150 mg, volume 6 ml, 30 pcs/pack MAX 固相萃取小柱 | / | 994507 |
| Microporous membrane filters, CA, non-sterile, white, Ф47, 0.45μm, 50 pcs/pack 微孔滤膜 | / | 986357 |
| MCE syringe filter, non-sterile, 25 mm, 0.22 µm, 100 pcs/pack 水系混合纤维素针式过滤器 | / | 9217640 |
| Short screw thread vials, 2ml, 9mm, 11.6×32mm, with marking spot, amber, wide opening 短螺纹样品瓶 | / | 902590 |
| Short screw thread vial caps and septa, 9 mm blue pp cap, centre hole 6 mm, pre-slit blue PTFE/white silicone septum 短螺纹样品瓶组合盖垫 | / | 993144 |
| Syringe filter, PTFE membrane (hydrophillic), non-sterile, 13mm, 0.45µm, 200 pcs/pack 针头式过滤器 | / | 2123704 |
| Single-channel mechanical pipettor, Volume range: 50 - 200 μL, Increment: 1.0 μL 单道手动可调移液器 | / | 997681 |
| Pipette tips, 200 μL, yellow, low Retention, 1000 tips/pack 移液器吸头 | / | 1438546 |
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