铜族金属热活化延迟荧光配合物及 OLED 技术：进展与应用前景-百灵威

近年来，基于铜族金属铜、银和金的系列二配位配合物作为一类新兴的热活化延迟荧光（TADF）发光材料，在光致发光机理研究、电致发光器件以及光催化等领域展现出巨大的应用潜力。

北京科技大学李天一教授团队成功制备了一系列构型可调的 Cu（Ⅰ）TADF 配合物。该配合物的转动受限扭曲构型有效抑制了非辐射跃迁能量损失，在蓝光 TADF 配合物中获得了 74% 的高光致发光效率和 1.9 ms 的快速 TADF 发光寿命。在掺杂发光层器件中，最大外量子效率可达 20%；即使在非掺杂器件中，最大外量子效率也能达到 10%，且在 100 cd/m² 亮度下，器件效率滚降小于 2%。

百灵威独家供应李天一教授课题组开发的一系列铜族金属热活化延迟荧光配合物，这些配合物结构多样，性能优异且稳定性良好，拥有广阔的应用前景。

Cu（I）TADF 配合物产品优势及详情：

1.性能参数优异：△EST低至120meV；kr,S1 高达1.3×10⁵ s⁻¹；光致发光效率高至74%；TADF的快速发光寿命为1.9 ms 。
2.电致发光性能佳：在真空蒸镀OLED器件的掺杂发光层中，最大外量子效率达到 20% ；非掺杂器件中，最大外量子效率达到10%；在100 cd/m²亮度下，器件效率滚降小于2% 。
3.结构与构型可调：以吲哚类衍生物为芳胺配体，在吲哚2位引入不同空间位阻及电荷效应的取代基，配合物构型能从共平面调节至45°扭曲以及正交。
4.抑制能量损失：转动受限的扭曲构型抑制了非辐射跃迁能量损失。
5.综合优势显著：与磷光贵金属铱铂配合物相比，发光效率高、发射寿命短、发光颜色调节灵活、稳定性好；成本低廉、制备难度低。

产品详情

品名	CAS	货号
MAC(Cu)CzCN2, 99% MAC(Cu)CzCN2	2328069-21-0	9419141
MAC(Cu)CzCN, 99% MAC(Cu)CzCN	2328069-22-1	9419142
MAC(Cu)Cz, 99% MAC(Cu)Cz	2311939-76-9	9419143
DAC(Cu)CzCN2, 99% DAC(Cu)CzCN2	2328069-23-2	9419144
DAC(Cu)CzCN, 99% DAC(Cu)CzCN	2328069-24-3	9419145
MAC(Ag)Cz, 99% MAC(Ag)Cz	2311939-50-9	9419146
MAC(Au)Cz, 99% MAC(Au)Cz	2311939-51-0	9419147
DAC(Au)4-diphenylaminophenyl, 99% DAC(Au)4-二苯基氨基苯基	2412140-45-3	9419148
Salicyloylaminotriazole 水杨酰胺基三唑	36411-52-6	A3646
MAC(Au)4-diphenylaminophenyl, 99% MAC(Au)4-二苯基氨基苯基	2412140-48-6	9419149
MAC(Cu)DPAC, 99% MAC(Cu)DPAC	2830586-97-3	9419151
MAC(Au)4-dimethylaminophenyl, 99% MAC(Au)4-二甲氨基苯基	2412140-49-7	9419150
MAC(Cu)(2-CF3)Indole, 99% MAC(Cu)(2-CF3)Indole	/	9419152
Ammonium Tetrachloroplatinate(II) 四氯铂(II)酸铵	13820-41-2	A3668
MAC(Cu)Indole, 99% MAC(Cu)Indole	/	9419153
MAC(Cu)-2,3-dimethyl-indole, 99% MAC(Cu)-2,3-二甲基吲哚	/	9419154
MAC(Cu)TetraHCz, 99% MAC(Cu)TetraHCz	/	9419155
MAC(Cu)(2-Phenyl-Indole), 99% MAC(Cu)(2-苯基吲哚)	/	9419156
MAC(Cu))(3-CF3Cz), 99% MAC(Cu))(3-CF3Cz)	/	9419157
DAC(Cu))(3-CF3Cz), 99% DAC(Cu))(3-CF3Cz)	/	9419158
DAC(Cu))(3,6-CF3Cz), 99% DAC(Cu))(3,6-CF3Cz)	/	9419159

OLED系列其他产品推荐：

有机发光材料

品名	CAS	货号
Perylene, 98% 苝	198-55-0	964559
PFN-Br, 98% PFN-溴	889672-99-5	2573654
1,7-Dibromo-3,4,9,10-tetracarboxylic acid dianhydride, 98% 1,7-二溴-3,4,9,10-苝四羧基双酐	118129-60-5	1593715
Tris(8-quinolinolato)aluminum, 99% 三(8-羟基喹啉)铝	2085-33-8	237914
Tris(2-phenylpyridinato)iridium(III), 98%, purified by sublimation 三(2-苯基吡啶)合铱(III)	94928-86-6	956819
4,4'-Bis(9H-carbazol-9-yl)biphenyl, 99.5%, purified by sublimation 4,4'-双(9H-咔唑-9-基)联苯	58328-31-7	214030
3,4,9,10-Perylenetetracarboxylic dianhydride, 98% 3,4,9,10-苝四甲酸二酐	128-69-8	241614
3,4,9,10-Perylenetetracarboxylic diimide, 95% 3,4,9,10-苝四甲酰二亚胺	81-33-4	459318
4,6-Dibromodibenzothiophene, 99% 4,6-二溴二苯并噻吩	669773-34-6	1557064
Anthracene, 98.5% 蒽	120-12-7	458606 危化品
Tris[2-(4,6-difluorophenyl)pyridinato-C2,N]iridium(III), 97% 三[2-(4,6-二氟苯基)吡啶-C2,N]铱(III)	387859-70-3	807348
(2-Methoxynaphthalen-1-yl)boronic acid, 98% 2-甲氧基-1-萘基硼酸	104116-17-8	890275
Rubrene, 98.5% 红荧烯	517-51-1	223497
2',7'-Dimethylspiro[[cyclopenta, 95% 2'7'-二甲基-4,5-二氮杂螺芴氧杂蒽	2000250-49-5	2405801
PFN-Br, 98% PFN-溴	889672-99-5	2573654
Poly(N-vinylcarbazole), average M.W. 90,000 聚(N-乙烯基咔唑)	25067-59-8	344710
Phenanthridine, 98% 菲啶	229-87-8	279465
Tris[1-phenylisoquinoline-C2,N]iridium(III), 97% 三[1-苯基异喹啉-C2,N]铱(III)	435293-93-9	945049
2-Aminodibenzofuran, 98% 2-氨基二苯并呋喃	3693-22-9	1429290
dibenzo[b,d]furan-2-ylboronic acid, 99% 2-氧芴硼酸	402936-15-6	1554642
N-([1,1'-biphenyl]-4-yl)dibenzo[b,d]thiophen-2-amine, 99% N([1.1'联苯]-4-基）硫芴-2-胺	1300028-93-6	9228985
2',7'-Dimethylspiro[[cyclopenta, 95% 2'7'-二甲基-4,5-二氮杂螺芴氧杂蒽	2000250-49-5	2405801
Benz[b]anthracene, 97% 苯并[B]蒽	92-24-0	119820
Coumarin 30, 98% 香豆素 30	41044-12-6	310303
Poly-TPD, average MW: 10,000 - 100,000 聚[双(4-苯基)(4-丁基苯基)胺]	472960-35-3	1769701
[Ir(dtbbpy)(ppy)2]PF6, 97% (4,4'-二叔丁基-2,2'-联吡啶)双[(2-吡啶基)苯基]铱(III)六氟磷酸盐	676525-77-2	1836092
Phencyclone, 97% 9,10-菲并1,12-二苯基环戊二烯酮, 97%	5660-91-3	L00108
2,2'-Dibromobiphenyl, 98% 2,2'-二溴联苯	13029-09-9	243082
2,2'-Bis(trifluoromethyl)benzidine, 99% 2,2'-双(三氟甲基)二氨基联苯	341-58-2	126674
1-Naphthylamine, 99% 1-萘胺	134-32-7	253305 危化品
2,4-Dinitro-1-naphthol 2,4-二硝基-1-萘酚	605-69-6	D0839 危化品
PTAA-3Me Poly[bis(4-phenyl)(2,4,6-triMethylphenyl)aMine]	1333317-99-9	PH0999
PTAA-2Me 光电试剂	313996-10-0	PH0100
PTAA-F PTAA-F试剂	618108-64-8	PH0648
PTAA-2F PTAA-2F	/	PH0104
4,4-Bis(2,2’-diphenylethenyl)-1,1’-biphenyl DPVBi	142289-08-5	BD0510
Cadmium selenide StremDots? quantum dot (CdSe core) kit, 50umol/L in hexanes, 525-625nm peak emissions 硒化镉	1306-24-7	96-0800 危化品

发光金属配合物

此外，还有一些发光金属配合物要介绍，这是一类由金属离子与有机配体通过配位键构成，是发光材料重要类别。它发光效率高、颜色易调、稳定性好，在光电器件、生物医学、化学传感等领域广泛应用。

品名	CAS	货号
8-Hydroxyquinoline zinc, 98% 8-羟基喹啉锌盐	13978-85-3	151326
Tris(2,2'-bipyridine)ruthenium(II) bis(hexafluorophosphate), 98% 三(2,2'-联吡啶)钌(II)二(六氟磷酸)盐	60804-74-2	988227
Tris(2,2'-bipyridyl)ruthenium(II)chloride hexahydrate, 98% 三(2,2’-联吡啶基)氯化钌(II)六水合物	50525-27-4	102033
Tris(2-phenylpyridinato)iridium(III), 98%, purified by sublimation 三(2-苯基吡啶)合铱(III)	94928-86-6	956819
Tris(4,7-diphenyl-1,10-phenanthroline)ruthenium (II) dichloride 三( 4,7-联苯-1,10-邻菲啰啉)二氯化钌	36309-88-3	241557
Tris(8-quinolinolato)aluminum, 99% 三(8-羟基喹啉)铝	2085-33-8	237914
Tris(dibenzoyl methane)mono(phenan throline)europium (III), 95% 三(二苯甲酰基甲烷)单(菲罗啉)铕(III)	17904-83-5	154770
Bis[2-(2-benzothiazolyl)phenolato]zinc(II), 98% 双[2-(2-苯并噻吩基)苯酚]锌(II)	58280-31-2	545466

热延迟荧光配合物

热延迟荧光配合物是特殊的有机发光材料，通过单重态与三重态间的系间窜越及热激活反向系间窜越发光。它理论内部量子效率达 100%，无需重金属，兼具高效、低成本与低毒性优势。在 OLED 显示、照明和生物成像等领域，热延迟荧光配合物极具应用前景，为高性能发光器件提供新材料。

品名	CAS	货号
2,3-TXO-PhCz, 99% 2,3-TXO-PhCz	2379245-90-4	9186352
2,6-TXO-PhCz, 99% 2,6-TXO-PhCz	2379245-92-6	9186350
2,7-TXO-PhCz, 99% 2,7-TXO-PhCz荧光材料	2058053-98-6	9186351
2-(9-Phenyl-9H-carbazol-3-yl)-10,10-dioxide-9H-thioxanthen-9-one, 99%, sublimed 2-(9-苯基-9-氢-咔唑-3-基)-10,10-二氧-9-氢-噻吨-9-酮	1623010-64-9	2698361
2-[4-(Diphenylamino)phenyl]-10,10-dioxide-9H-thioxanthen-9-one, 99%, sublimed 2-(4-二苯胺基)苯基-10,10-二氧-9-氢-噻吨-9-酮	1623010-63-8	2698362
2F-BTH-DMF, 99% 2F-BTH-DMF	2045350-88-5	9186346
3,6-TXO-PhCz, 99% 3,6-TXO-PhCz	2055653-05-7	9186349
BTH-DMF, 99% BTH-DMF荧光材料	333432-18-1	9186345
SDPS-4PhCz, 99% SDPS-4PhCz	/	9186343
f-TX-TPA, 99% f-TX-TPA	2379627-81-1	9186348
o-BTH-DMF, 99% o-BTH-DMF荧光材料	2413845-07-3	9186347

空穴注入层材料

品名	CAS	货号
PEDOT: PSS（CLEVIOS™ P VP AI 4083）, from Heraeus PEDOT: PSS, 型号为4083	155090-83-8	927751
HAT-CN6, 99%, sublimed grade HAT-CN6	105598-27-4	992281
2,3,5,6-Tetrafluoro-7,7,8,8-tetracyanoquinodimethane, 98% 2,3,5,6-四氟-7,7,8,8-四氰二甲基对苯醌	29261-33-4	947622
Molybdenum trioxide, 99% 三氧化钼	1313-27-5	203179
Tungsten(VI) oxide, 99% 三氧化钨(VI)	1314-35-8	339310
Vanadium(V) oxide, 99%, for synthesis 五氧化二钒	1314-62-1	972308 危化品
Nickel oxide, 99%, particle size: 4-8nm, 2.5wt.% in n-hexanol colloidal dispersion 氧化镍	/	113317

电子注入层材料

品名	CAS	货号
Lithium fluoride, 99.99% 氟化锂	7789-24-4	921298 危化品
Cesium carbonate, 99.9%, for synthesis 碳酸铯	534-17-8	904086
Zinc oxide, 99.99%, trace metals basis 氧化锌	1314-13-2	955126
Titanium(III) oxide, 99.9%, 100 mesh 氧化钛(III)	1344-54-3	500198
4,7-Diphenyl-1,10-phenanthroline, 98.5% 4,7-二苯基-1,10-菲咯啉	1662-01-7	295717
Bathocuproine, 99% 2,9-二甲基-4,7-二苯基-1,10-菲咯啉	4733-39-5	231472
Polyethyleneimine, 99%, M.W. 600 聚乙烯亚胺	9002-98-6	921258
PFN-DOF, average M.W. 10,000 PFN-DOF缓冲层材料	673474-75-4	2575548
Graphene oxide, 99%, reagent grade, thickness: 0.55 - 1.2 nm, diam.: 0.5 - 3 μm, layers: ＜3 氧化石墨烯	1034343-98-0	934143
Graphene, 98%, reagent grade, thickness: 0.55 - 3.74 nm, diam.: 0.5-3μm, layers: <1 石墨烯	1034343-98-0	966627
Aluminum hydroxide terephthalate MOF, Aperture: 0.8nm * 1.3nm, Particle size: 5 - 10μm, BET specific surface area: 900 - 1100 m2/g 对苯二甲酸铝	654061-20-8	948668

空穴传输层材料

品名	CAS	货号
2,2’,7,7’-Tetrakis-(N,N-di-4-methoxyphenylamino)-9,9’-spirobifluorene, 98% 2,2',7,7'-四[N,N-二(4-甲氧基苯基)氨基]-9,9'-螺二芴	207739-72-8	920726
Phthalocyanine Blue 15, 93% 酞菁蓝15	147-14-8	300617
4,4'-Bis[N-(1-naphthyl)-N-phenylamino]biphenyl, 99% 4,4'-双[N-(1-萘基)-N-苯氨基]联苯	123847-85-8	171244
2,2’,7,7’-Tetrakis-(N,N-di-4-methoxyphenylamino)-9,9’-spirobifluorene, 99.5%, for perovskite solar cell 2,2',7,7'-四[N,N-二(4-甲氧基苯基)氨基]-9,9'-螺二芴	207739-72-8	965749
Poly-TPD, average MW: 10,000 - 100,000 聚[双(4-苯基)(4-丁基苯基)胺]	472960-35-3	1769701
2,3,5,6-Tetrafluoro-7,7,8,8-tetracyanoquinodimethane, 95% 2,3,5,6-四氟-7,7,8,8-四氰二甲基对苯醌	29261-33-4	576478
4,4',4''-Tris(carbazol-9-yl)triphenylamine, 98% 4,4',4"-三(咔唑-9-基)三苯胺	139092-78-7	537710
4,4',4''-Tris[2-naphthyl(phenyl)amino]triphenylamine, 98% 4,4',4''-三[2-萘基(苯基)氨基]三苯胺	185690-41-9	941365
Aluminum phthalocyanine chloride, 98%, purified by sublimation 酞菁氯化铝	14154-42-8	105067
Cobalt phthalocyanine, 92% 酞菁钴	3317-67-7	309305
Poly(N-vinylcarbazole), average M.W. 90,000 聚(N-乙烯基咔唑)	25067-59-8	344710
Titanyl phthalocyanine, 95% 氧钛酞菁	26201-32-1	516413
Tri-p-tolylamine, 98% 三对甲苯基胺	1159-53-1	597062
4,4'-Bis(9H-carbazol-9-yl)biphenyl, 99.5%, purified by sublimation 4,4'-双(9H-咔唑-9-基)联苯	58328-31-7	214030
Poly(N-vinylcarbazole), average M.W. 90,000 聚(N-乙烯基咔唑)	25067-59-8	344710
Phenanthridine, 98% 菲啶	229-87-8	279465
4,4'-Bis(9H-carbazol-9-yl)biphenyl, 99.5%, purified by sublimation 4,4'-双(9H-咔唑-9-基)联苯	58328-31-7	214030
N,N,N',N'-Tetrakis(p-tolyl)benzidine, 98% N,N,N',N'-四(对甲苯基)联苯胺	76185-65-4	454789
1-bromo-4-chloronaphthalene, 99% 1-溴-4-氯萘	53220-82-9	1968999
2,4-Bis-biphenyl-4-yl-6-chloro-[1,3,5]triazine, 98.0% 2,4-二([1,1'-联苯]-4-基)-6-氯-1,3,5-三嗪	182918-13-4	1570355
F6-TCNNQ F6-TNAP	912482-15-6	OS2156

电子传输层材料

品名	CAS	货号
1,3,5-Tris(1-phenyl-2-benzimidazolyl)benzene, 99% 1,3,5-三(1-苯基-1H-苯并咪唑-2-基)苯	192198-85-9	925947
1,3-Bis[5-(4-tert-butylphenyl)-2-[[1,3,4]oxadiazolyl]benzene, 99%, purified by sublimation 1,3-双[5-(4-叔丁基苯基)-2-[[1,3,4]恶二唑基]苯	138372-67-5	915113
2,4,6-Triphenyl-1,3,5-triazine, 98% 2,4,6-三苯基-1,3,5-三嗪	493-77-6	912668
2,5-Diphenyl-1,3,4-oxadiazole, 97% 2,5-二苯基-1,3,4-恶二唑	725-12-2	314105
1,4,5,8-Naphthalenetetracarboxylic dianhydride, 97.5% 1,4,5,8-萘四甲酸二酐	81-30-1	272094
2-(4-Tert-butylphenyl)-5-(4-biphenylyl)-1,3,4-oxadiazole, 99% 2-(4-对叔丁基苯基)-5-(4-联苯基)-1,3,4-噁二唑	15082-28-7	304467
4,7-Diphenyl-1,10-phenanthroline, 98.5% 4,7-二苯基-1,10-菲咯啉	1662-01-7	295717
BBOT, 98% 荧光增白剂OB, 2,5-双(5-叔丁基-2-苯并恶唑基)噻吩	7128-64-5	536133
O-IDTBR, 98% O-IDTBR	2077945-91-4	922173
Bathocuproine, 99% 2,9-二甲基-4,7-二苯基-1,10-菲咯啉	4733-39-5	231472
Tris(8-quinolinolato)aluminum, 99.5%, purified by sublimation 三(8-羟基喹啉)铝	2085-33-8	982217
4,7-Diphenyl-1,10-phenanthroline, 98.5%, reagent grade 4,7-二苯基-1,10-菲咯啉	1662-01-7	934332
Zinc oxide, 99%, ACS reagent 氧化锌	1314-13-2	547856

电极材料及合成用试剂

品名	CAS	货号
Indium tin oxide, 99.99%, metal basis, 300 mesh, In2O3, 90 wt%; SnO2, 10 wt% 氧化铟锡	50926-11-9	227355
PEDOT: PSS（CLEVIOS™ P VP AI 4083）, from Heraeus PEDOT: PSS, 型号为4083	155090-83-8	927751
Tin(II) chloride, 98% 氯化亚锡(II)	7772-99-8	998762
Indium(III) chloride, 99.999%, anhydrous, trace metals basis 氯化铟	10025-82-8	473706
Zinc chloride, 97%, ACS reagent 氯化锌	7646-85-7	912611 危化品
Aluminum nitrate nonahydrate, 99%, AR 硝酸铝九水合物	7784-27-2	510205 危化品

合成用金属盐

品名	CAS	货号
Iridium(III) chloride, Ir≥63.9% 氯化铱	10025-83-9	997634
Cadmium chloride, anhydrous (99.995%-Cd) PURATREM 氯化镉	10108-64-2	48-1500 危化品
Zirconium(IV) chloride (99.5+%-Zr) 氯化锆	10026-11-6	93-4045 危化品
Gallium(III) chloride, anhydrous, fused lump (99.999%-Ga) PURATREM 氯化镓	13450-90-3	93-3141
Ammonium chloride, 99.6%, ACS reagent 氯化铵	12125-02-9	934775
Cerium(III) chloride, 99.9%, anhydrous 氯化铈(III)	7790-86-5	125652
Cesium chloride, 99.99% 氯化铯	7647-17-8	926782
Cobalt(II) chloride, 97%, anhydrous 氯化钴(II)	7646-79-9	989962 危化品
Copper(I) chloride, 99.99% 氯化亚铜(I)	7758-89-6	931651
Magnesium chloride, 98% 氯化镁	7786-30-3	266646
Rhodium(III) chloride, 98% 氯化铑(III)	10049-07-7	398503
Nickel(II) chloride, 98%, anhydrous 氯化镍(II)	7718-54-9	120836 危化品
Iron(II) chloride, 99.99%, anhydrous 氯化铁(II)	7758-94-3	960107
Chromium(III) chloride, 99% 三氯化铬	10025-73-7	932185
Indium(III) chloride tetrahydrate, 98% 氯化铟(III) 四水合物	22519-64-8	956956
Aluminum chloride, 99%, trace metals basis 三氯化铝	7446-70-0	290063 危化品
Ruthenium(III) chloride, 99%, anhydrous 三氯化钌(III)	10049-08-8	257385
Tantalum(V) chloride, 99.9% 五氯化钽(V)	7721-01-9	296141 危化品
Tungsten(VI) chloride, 99.5% 六氯化钨(VI)	13283-01-7	337438
Potassium Tetrachloroplatinate(II) 氯亚铂酸钾	10025-99-7	SY011802
Aluminium nitrate nonahydrate, 99+%, for analysis 硝酸铝九水合物	7784-27-2	C21828 危化品
Cerium(III) nitrate hexahydrate, 99%, reagent grade 硝酸铈(III)六水合物	10294-41-4	194803 危化品
Europium(III) nitrate hexahydrate, 99.9% 硝酸铕(III) 六水合物	10031-53-5	142991
Iron(III) nitrate nonahydrate, 98%, ACS reagent 硝酸铁(III)九水合物	7782-61-8	487605
Copper(II) nitrate trihydrate, 99.5% 硝酸铜(II)三水合物	10031-43-3	923629 危化品
Rubidium nitrate 硝酸铷	13126-12-0	F988102
Rhodium(III) nitrate 硝酸铑	10139-58-9	099767 危化品
Ammonium cerium(IV) nitrate, 98%, for synthesis 硝酸铈铵	16774-21-3	922395 危化品
Manganese nitrate, for analysis, 50 wt.% solution in H2O 硝酸锰	10377-66-9	406741 危化品
Copper(II) nitrate trihydrate (99.999%-Cu) PURATREM 硝酸铜	10031-43-3	93-2940 危化品
Rhodium(III) nitrate, solution in water (10% Rh) 硝酸铑溶液	10139-58-9	45-1808 危化品
硝酸锂硝酸锂	7790-69-4	229741 危化品
硝酸钯(II) 溶液硝酸钯(II) 溶液	868605-16-7	380040
Cobalt nitrate hexahydrate, 99%, for analysis 硝酸钴六水合物	10026-22-9	949153 危化品
Cerium(III) nitrate hexahydrate (99.99%-Ce) (REO) PURATREM 硝酸铈六水合物	10294-41-4	93-5814 危化品